. Determine the Factors affecting the magnitude of electron affinity


Best Answer

Factors affecting the magnitude of electron affinity :

1. Atomic size: In general electron affinity value decreases with the increasing atomic radius because electrostatic force of attraction decreases between the electron being added and the atomic nucleus due to increase of distance between them.

2. Effective nuclear charge:Electron affinity value of the element increase as the effective nuclear charge on the atomic nucleus increases because electrostatic force of attraction between the electron being added and the nucleus increases. As the electrostatic force of attraction increases, amount of energy released is more

3. Screening or Shielding effect:Electron affinity value of the elements decreases with the increasing shielding or screening effect. The shielding effect between the outer electrons and the nucleus increases as the number of electrons increases in the inner shells.

4. Stability of half filledand completely filled orbitals: The stability of half filled and completely filled degenerate orbitals of a sub shell is comparatively more, so it is difficult to add electron in such orbitals and lesser energy is released on addition of electron hence the electron affinity value will decrease.

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