The three chapters Dual Nature of Radiation and Matter, Atoms, and Nuclei connect some of the most important ideas in modern physics. Questions often require you to identify the correct formula, interpret a graph, calculate an energy difference or predict how a nucleus changes during decay.
Use Physics Wallah’s Dual Nature of Radiation and Matter, Atoms and Nuclei Important Questions to practise numerical problems, revise frequently tested relationships and strengthen your understanding of concepts that are easy to confuse.
Answer: The de Broglie wavelength is the wavelength associated with a moving material particle.
The formula is:
λ = h/p
For a non-relativistic particle, momentum is p = mv. Therefore:
λ = h/mv
Where:
λ = de Broglie wavelength
h = Planck’s constant = 6.626 × 10⁻³⁴ J s
p = momentum
m = mass of the particle
v = velocity of the particle
If the kinetic energy K is given, use:
λ = h/√(2mK)
Key point: A particle’s wavelength decreases as its momentum increases.
Answer: A charged particle accelerated through a potential difference V gains kinetic energy.
For a particle of mass m and charge magnitude q, assuming it starts from rest:
qV = K = ½mv²
Using λ = h/√(2mK):
λ = h/√(2mqV)
This formula applies to a non-relativistic particle accelerated from rest through a potential difference V.
Answer: For an electron accelerated through V volts, the approximate formula is:
λ = 12.27/√V Å
Here, V is the accelerating potential in volts and Å represents angstroms.
Example: An electron is accelerated through 100 V. Find its de Broglie wavelength.
λ = 12.27/√100 Å
λ = 12.27/10 Å
λ = 1.227 Å
This is a useful relation for numerical questions involving electrons.
Answer: For a gas molecule whose kinetic energy is taken as the average translational kinetic energy,
K = 3kT/2
Substituting into λ = h/√(2mK):
λ = h/√(3mkT)
Where k is Boltzmann’s constant and T is the absolute temperature in kelvin.
Remember: Select the formula according to the kinetic energy specified in the question. The expression above uses average translational kinetic energy, not the kinetic energy of every individual molecule.
Answer: Both matter particles and photons have a de Broglie wavelength given by:
λ = h/p
For a non-relativistic material particle:
λ = h/mv
For a photon:
E = pc = hc/λ
Therefore:
λ = hc/E
A photon has zero rest mass but carries energy and momentum.
Answer: Radiation pressure is the force exerted by electromagnetic radiation per unit area on a surface.
For radiation of intensity I incident normally on an area A:
|
Surface |
Force |
Radiation pressure |
|
Perfectly absorbing |
F = IA/c |
P = I/c |
|
Perfectly reflecting |
F = 2IA/c |
P = 2I/c |
Here, c is the speed of light.
Key point: For normal incidence, a perfectly reflecting surface experiences twice the radiation pressure of a perfectly absorbing surface under the same incident intensity.
Answer: If radiation of intensity I falls normally on an area A, the incident power is:
P = IA
Energy of one photon:
E = hν = hc/λ
If N represents the number of photons incident per unit time, then:
N = P/hν
Therefore:
N = IA/hν = IAλ/hc
You can also use:
N = Pλ/hc
Example: A light source delivers power P at frequency ν. The number of photons arriving per second is P divided by hν.
Remember that N here means a photon rate, measured in photons per second.
Answer: The photoelectric effect is the emission of electrons from a material surface when incident electromagnetic radiation has a sufficiently high frequency.
The emitted electrons are called photoelectrons, and the resulting flow of charge is measured as photoelectric current.
The effect demonstrates the particle nature of light because the energy transferred to an electron depends on the energy of an individual photon.
Answer: Threshold frequency, ν₀, is the minimum frequency required to cause photoelectric emission from a particular material.
If ν > ν₀, photoelectric emission occurs.
If ν = ν₀, emission can begin, with zero maximum kinetic energy in the ideal case.
If ν < ν₀, photoelectric emission does not occur, regardless of the intensity of the incident light.
The work function is:
φ = hν₀
The threshold frequency depends on the material.
Answer: Einstein’s photoelectric equation follows conservation of energy. The energy of an incident photon is used to overcome the work function, and the remaining energy becomes the maximum kinetic energy of the emitted electron.
hν = φ + Kₘₐₓ
Since φ = hν₀:
Kₘₐₓ = hν − hν₀
The work function φ is the minimum energy required to remove an electron from the material surface.
Memory tip: Photon energy = Work function + Maximum kinetic energy.
Answer:
Photoelectric emission occurs only when the incident frequency is at or above the threshold frequency.
Increasing the frequency above threshold increases the maximum kinetic energy of the emitted electrons.
Increasing intensity at a fixed frequency above threshold generally increases the photoelectric current.
Photoelectric emission occurs with negligible time delay under ordinary experimental conditions.
Emitted electrons can have different kinetic energies because they originate from different energy states and may lose energy inside the material.
Answer: Stopping potential, Vₛ, is the minimum reverse potential needed to stop even the fastest photoelectrons from reaching the collector.
The relationship is:
Kₘₐₓ = eVₛ
Using Einstein’s equation:
eVₛ = hν − φ
Therefore:
Vₛ = (h/e)ν − φ/e
Where e is the magnitude of the electronic charge.
Answer: The graph of stopping potential Vₛ against incident frequency ν is a straight line.
From:
Vₛ = (h/e)ν − φ/e
Slope: h/e
Frequency-axis intercept: ν₀ = φ/h
Stopping-potential-axis intercept: −φ/e
For different metals, the slopes are the same in the ideal Einstein model because h/e is a universal constant. Metals with larger work functions have higher threshold frequencies and more negative stopping-potential-axis intercepts.
Answer: Cut-off wavelength, λ₀, is the maximum wavelength that can produce photoelectric emission from a given material.
Since frequency and wavelength are related by c = νλ:
φ = hν₀ = hc/λ₀
The photon energy is:
E = hν = hc/λ
A wavelength longer than λ₀ corresponds to photon energy below the work function, so photoelectric emission does not occur.
Answer: Write Einstein’s equation for each condition.
For two incident frequencies ν₁ and ν₂:
eVₛ₁ = hν₁ − φ
eVₛ₂ = hν₂ − φ
Subtracting eliminates the common work function:
e(Vₛ₂ − Vₛ₁) = h(ν₂ − ν₁)
Therefore:
h/e = (Vₛ₂ − Vₛ₁)/(ν₂ − ν₁)
This method is useful when two stopping potentials or two photoelectric conditions are given.
Answer: Thomson proposed that an atom consisted of a positively charged region with electrons embedded in it.
The model could not explain the results of Rutherford’s alpha-particle scattering experiment, particularly the large deflections experienced by a very small fraction of alpha particles. It was therefore replaced by the nuclear model of the atom.
Answer: Rutherford directed alpha particles at a thin gold foil and observed their scattering.
|
Observation |
Conclusion |
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Most alpha particles passed straight through |
Most of the atom is empty space |
|
Some alpha particles were deflected |
Positive charge is concentrated in a small region |
|
Very few alpha particles were deflected through large angles or returned backwards |
The atom contains a small, dense nucleus |
Memory tip: Straight passage indicates empty space; large-angle scattering indicates a small, dense, positively charged nucleus.
Answer: According to classical electromagnetic theory, a revolving electron is an accelerating charged particle and should continuously radiate energy.
As it lost energy, the electron would move towards the nucleus. Rutherford’s model could not explain why atoms remain stable or why they produce discrete line spectra.
Answer: Bohr proposed that electrons can occupy certain stable orbits without continuously radiating energy.
The main relations are:
Quantisation of angular momentum:
mvr = nh/2π
where n = 1, 2, 3, …
Energy of the nth orbit in a hydrogen-like atom:
Eₙ = −13.6Z²/n² eV
Radius of the nth orbit:
rₙ = 0.529n²/Z Å
Electron speed in the nth orbit:
vₙ ≈ 2.18 × 10⁶(Z/n) m/s
Here, Z is the atomic number of the hydrogen-like species.
An electron emits or absorbs a photon when it transitions between two permitted energy levels.
Answer: The energy of the photon equals the magnitude of the energy difference between the two levels.
For emission from a higher energy level nᵢ to a lower level n𝒻:
hν = Eᵢ − E𝒻
The photon wavelength is given by:
1/λ = RZ²(1/n𝒻² − 1/nᵢ²)
where nᵢ > n𝒻 and R is the Rydberg constant.
For absorption, the electron moves from a lower level to a higher level and absorbs a photon whose energy equals the energy difference.
Answer: If all possible downward transitions among the first n energy levels are considered, the maximum number of distinct spectral lines is:
N = n(n − 1)/2
Example: If an electron is initially in the fourth energy level:
N = 4(4 − 1)/2
N = 4 × 3/2
N = 6 spectral lines
This formula assumes that all possible transitions between the relevant levels can occur.
Answer: For an electron in a Coulomb-bound Bohr orbit:
Potential energy is negative.
Kinetic energy is positive.
Total energy is negative.
The relationships are:
U = −2K
E = K + U = −K = U/2
Example: If the potential energy is −8 eV:
K = −U/2 = +4 eV
E = K + U = 4 − 8
E = −4 eV
Answer: The ionisation energy is the energy required to remove the electron completely from that orbit.
Since:
Eₙ = −13.6Z²/n² eV
The ionisation energy from the nth orbit is:
Eᵢₒₙ = 13.6Z²/n² eV
For the ground state, n = 1:
Eᵢₒₙ = 13.6Z² eV
For hydrogen, Z = 1, so the ground-state ionisation energy is 13.6 eV.
Answer: A nucleus is represented as ᴬZX, where A is the mass number and Z is the atomic number.
Number of protons = Z
Number of neutrons = A − Z
Mass number = number of protons + number of neutrons
Example: For ²³₁₁Na:
Protons = 11
Neutrons = 23 − 11 = 12
Answer: Nuclear radius is approximately related to mass number by:
R = R₀A¹ᐟ³
where R₀ is approximately 1.2 fm and A is the mass number.
Since nuclear volume is proportional to R³, it is proportional to A. Nuclear mass is also approximately proportional to A. Therefore, nuclear density is approximately the same for different nuclei.
Answer: Mass defect is the difference between the sum of the masses of the separate constituent nucleons and the actual mass of the bound nucleus.
Δm = (sum of free nucleon masses) − (actual nuclear mass)
Binding energy is the energy required to separate the nucleus completely into its constituent nucleons.
BE = Δmc²
If the mass defect is expressed in atomic mass units:
BE (MeV) = Δm (u) × 931.5
Answer: Binding energy per nucleon is the average binding energy associated with each nucleon.
Binding energy per nucleon = Total binding energy/A
A larger binding energy per nucleon generally indicates a more tightly bound nucleus and greater stability against separation into individual nucleons.
Nuclei around the iron-nickel region have among the highest binding energies per nucleon. This helps explain why energy can be released by fission of very heavy nuclei and fusion of sufficiently light nuclei.
Answer: The changes depend on the type of radioactive decay.
|
Decay type |
Change in atomic number Z |
Change in mass number A |
|
Alpha decay |
Decreases by 2 |
Decreases by 4 |
|
Beta-minus decay |
Increases by 1 |
No change |
|
Beta-plus decay |
Decreases by 1 |
No change |
|
Gamma emission |
No change |
No change |
Examples:
Alpha decay:
ᴬZX → ᴬ⁻⁴Z⁻²Y + ⁴₂He
Beta-minus decay:
ᴬZX → ᴬZ+1Y + e⁻ + antineutrino
Beta-plus decay:
ᴬZX → ᴬZ−1Y + e⁺ + neutrino
Gamma emission releases energy from an excited nucleus without changing its atomic number or mass number.
Answer: An alpha particle contains two protons and two neutrons. When a nucleus emits an alpha particle:
Its atomic number decreases by 2.
Its mass number decreases by 4.
The released energy is shared between the alpha particle and the recoiling daughter nucleus, with the exact distribution depending on the decay and conservation of momentum.
Answer:
Beta-minus decay: A neutron changes into a proton, emitting an electron and an antineutrino. The atomic number increases by 1.
Beta-plus decay: A proton changes into a neutron, emitting a positron and a neutrino. The atomic number decreases by 1.
Electron capture: The nucleus captures an inner-shell electron. A proton changes into a neutron, and the atomic number decreases by 1.
In all three processes, the mass number remains unchanged.
Revise these questions by first identifying the concept being tested, then selecting the relevant formula and checking the units before calculating. Pay particular attention to photoelectric graphs, Bohr energy transitions, radioactive decay and binding energy. Physics Wallah’s Physics Important Questions can support your preparation by helping you practise these concepts and strengthen your numerical problem-solving.
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