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Radioactivity And The Law

Explore the concept of radioactivity and its legal implications. Understand activity, half-life, and mean life in this comprehensive guide.
authorImageAbhishek Kumar14 Nov, 2023
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Radioactivity And The Law

M. Curie and P. Curie with Becquerel, were awarded the Nobel Prize in Physics for their discovery of Radioactivity, in 1903.

Radioactivity is the phenomenon of spontaneous disintegration, attended by emission of electromagnetic radiations, of heavy atomic nuclei like Uranium, Radium, etc. at a constant rate unaffected by any physical or chemical changes or influences such as temperature, pressure, etc. to which the atom may be subjected. It is a nuclear property of the active element and in all radioactive processes. There are three features of radioactivity from the perspective of classical physics:
  • When a nucleus undergoes alpha or beta decay, its atomic number Z changes and it becomes the nucleus of a different element.
  • The energy liberated during radioactive decay comes from within individual nuclei without external excitation, similar to the case of atomic radiation.
  • Radioactive decay is a statistical process that obeys the law of chance i.e. a certain probability per unit time.
The Radioactivity of an element arises from the radioactivity of one or more of its isotopes. Most elements in nature have no radioactive isotopes, although such isotopes can be prepared artificially and are useful in biological and medical research as “tracers”. Other elements such as potassium have some stable isotopes and some radioactive ones such as uranium have only radioactive isotopes. Earlier experiments by Rutherford and his coworkers, define three components in radiations from radionuclides such as alpha, beta, and gamma later positron emission and electron capture were added to the list of decay modes.

Law of Radioactive Decay

On emission of or rays, which is usually but not invariably accompanied by - ray emission, the emitting parent nuclei transform into new daughter elements. The daughter element is again radioactive so that the process of successive disintegration continues till parent nuclei transform into stable ones.
  1. Activity: The activity of a sample of any radioactive nuclide is the rate at which the nuclei of its constituent atoms decay.
If N is the number of nuclei present in the sample at a certain time, its Activity R is given by:

R = - dN / dt

The minus sign is used to make R a positive quantity since dN / dt is a negative quantity. The SI unit of activity is named after Becquerel:

1 becquerel = 1 B q = 1 decay/s

The other unit of activity is Curie(Ci), which is defined as 1 g of radium Ra 88 226 .

1 curie = 1 Ci = 3.70 10 10 decay/s = 37 GB q

The most important single source is the radioactive gas radon, a decay product of radium traces back to the decay of uranium. Uranium is found in many common rocks such as granite. Hence radon, colorless or odorless, is present nearly everywhere, usually in small amounts to endanger health. As a cause of lung cancer, radon is second only to cigarette smoking. Other natural sources of radiation dosage include cosmic rays from space and radionuclides present in rocks, soil, and building materials. Food, water, and the human body itself contain small amounts of radionuclides of such elements as potassium and carbon. The activities of radioactive samples show that it falls off exponentially with time. When the period starts, the activity drops to half of what it was at the start of the period. Every radionuclide has a characteristic half-life. Some half-lives are only millions of seconds and some are billions of years. One of the major problems faced by nuclear power plants is the safe disposal of radioactive waste since some nuclides have long half-lives. The time variation of activity follows the formula

R = R 0 e - λ t

Whereλ is a decay constant having a different value for each radionuclide.
  1. Half-life: The half-life of a radioactive nuclide is defined as the time T 1/2 in which the actual amount of radioactive atoms is reduced by way of disintegration to half its value. After a half-life has elapsed when t = T 1/2 the activity R drops to 1/2 R 0 . Hence,

1/2R 0 = R 0 e -λT 1/2

e - T 1/2 = 2

Taking logs on both sides, λ T 1/2 = ln2

T 1/2 = ln2/ = 0.693/ λ

The larger the decay constant, the greater the chance a given nucleus will decay in a certain period of time. If we assume a constant probability per unit of time for the decay of each nucleus of a given nuclide. With the probability per unit time, dt is the probability that any nucleus will undergo decay in a time interval dt. If a sample contains N undecayed nuclei, the number dN that decays in a time dt is the product of the number of nuclei N and the probability dt that each will decay in dt.

dN = -N λ dt

Where the minus sign indicates that N decreases as time increases. This formula gives the number N of undecayed nuclei at the time t in terms of the decay probability per unit time of the nuclide involved and the number N0 of undecayed nuclei at time t = 0. Every nucleus in a sample of a radionuclide has a certain probability of decaying but there is no way to know in advance which nuclei will actually decay in a particular time span. If the sample is large enough i.e. many nuclei are present the actual fraction of it that decay in a certain time span will be very close to the probability for any individual nucleus to decay.
  1. Mean Life or Average life: The average or mean lifetime T of all atoms in a given sample is defined as the reciprocal of its decay probability per unit of time:
The activity of a radioactive sample is defined as,

R = - dN/dt

R = N 0 e - λ t

R = λ N

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