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Difference Between Alcohol and Phenol

Alcohol and phenol, both containing hydroxyl groups, differ fundamentally. This topic is important from the NEET syllabus perspective and can be understood through the Difference Between Alcohol and Phenol table. Check it now.
authorImagePraveen Kushwah9 Jun, 2025
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Difference Between Alcohol and Phenol

Difference Between Alcohol and Phenol : Alcohol and phenol, both containing hydroxyl groups, differ fundamentally. Alcohols have hydroxyl groups attached to alkyl carbon atoms, classifying them as primary, secondary, or tertiary based on the carbon bonded to the hydroxyl group.

On the other hand, phenols exhibit a distinctive structure with the hydroxyl group directly attached to an aromatic benzene ring. This unique arrangement imparts distinct chemical behaviors to phenols. While alcohols and phenols share some common characteristics, such as the ability to undergo similar reactions, their classification and chemical reactivity set them apart.

Difference Between Alcohol and Phenol

Alcohols and phenols, despite both featuring hydroxyl groups, but show major differences. The structural differences arise from the attachment of the hydroxyl group in alcohols to alkyl carbon atoms, resulting in primary, secondary, or tertiary classifications. On the contrary, phenols display a unique configuration where the hydroxyl group directly bonds to an aromatic benzene ring. This difference influences their chemical behaviors. Alcohols, known for their diverse applications, particularly in beverages, differ substantially from phenols, which find use in pharmaceuticals as potent antiseptic agents. Understanding these variations is pivotal for their distinct applications and chemical roles.

Difference Between Alcohol and Phenol Overview

Here is the table below showcasing the Difference Between Alcohol and Phenol Overview based on all the parameters. This topic is crucial from the NEET exam syllabus, so NEET candidates must go through this table to improve their understanding of the concept.
Difference Between Alcohol and Phenol
Parameter Alcohol Phenol
Functional Group -OH (hydroxyl group) -OH (hydroxyl group) attached to an aromatic ring (benzene ring).
Structure Alcohols can be aliphatic or aromatic. Phenol is an aromatic compound with a benzene ring.
Aromaticity Does not contain an aromatic ring. Contains an aromatic benzene ring.
IUPAC Nomenclature Named as alkanols or phenols, depending on the structure. Specifically named as phenols due to the benzene ring.
Acidity Generally weak acids. Phenols are comparatively more acidic due to the resonance stabilization of the phenoxide ion.
Physical State at Room Temp. Can be liquid or solid, depending on the size and structure. Typically solid at room temperature due to stronger intermolecular forces.
Solubility in Water Soluble in water. Soluble in water but less so than alcohols due to stronger intermolecular forces in phenols.
Reactivity with Metals Reacts with active metals to produce hydrogen gas. Does not react with active metals to produce hydrogen gas.
Example Ethanol (C2H5OH), Methanol (CH3OH). Phenol (C6H5OH).

What is Alcohol?

Alcohol is a class of organic compounds characterized by the presence of a hydroxyl (-OH) group attached to a carbon atom. Alcohols can be classified into primary, secondary, or tertiary based on the number of carbon atoms directly attached to the carbon carrying the hydroxyl group. Common examples include methanol (CH₃OH), ethanol (C₂H₅OH), and isopropyl alcohol (C₃H₇OH).

What is Phenol?

Phenol is an aromatic organic compound consisting of a hydroxyl (-OH) group attached to a benzene ring. It is both an alcohol and a benzene derivative. Phenol exhibits unique properties due to its aromatic structure. Commonly used as an antiseptic and in the production of various chemicals, phenol plays a significant role in industries. Its simplest form is represented by the chemical formula C₆H₅OH. NEET Study Material Elevate your NEET exam preparedness with PW NEET online coaching . Our expert tutors, interactive classes, and comprehensive study materials ensure that you are fully prepared for success. Join PW’s online courses and Excel in your NEET journey.
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Difference Between Alcohol and Phenol FAQs

What is the Difference between Alcohol, Phenol, and Ether in Class 12

Alcohol: Alcohols have the general formula R-OH, where R is an alkyl group. They contain a hydroxyl (-OH) functional group attached to a saturated carbon atom. Phenol: Phenol (C₆H₅OH) is an aromatic compound with a hydroxyl group attached to a benzene ring. Ether: Ethers have the general formula R-O-R', where R and R' are alkyl or aryl groups. They consist of an oxygen atom bonded to two carbon atoms.

What is the Difference between Phenol and Primary Alcohol

Phenol: Phenol is an aromatic compound with a hydroxyl group directly attached to a benzene ring. It has unique properties due to its aromaticity. Primary Alcohol: Primary alcohols have the general formula R-CH₂OH, where R is an alkyl group. The hydroxyl group is attached to a carbon atom that is bonded to only one other carbon.

Why is Phenol not called Alcohol?

Phenol is not called an alcohol because it has distinct properties from typical alcohols. While it contains a hydroxyl group like alcohols, its aromatic nature and reactivity set it apart. Phenol's unique properties, including its acidity and aromatic ring structure, justify its separate classification.

What are the Difference between Phenol and Phenyl?

Phenol: Phenol is a specific compound (C₆H₅OH) consisting of a hydroxyl group attached to a benzene ring. It is both an aromatic compound and an alcohol. Phenyl: Phenyl is a functional group represented by C₆H₅, derived from removing one hydrogen atom from a benzene ring. It is an aryl group and is often found as part of larger compounds.
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