CBSE Class 11 Chemistry Notes Chapter 3: In ch 3 chemistry class 11 notes, we learn about how elements are grouped and organized based on their properties.
This organization helps us understand the behavior of different elements better. We study the periodic table, which is like a big chart showing all the elements arranged in a specific order.
This order is based on things like the number of protons in an atom and how the electrons are arranged around the nucleus. By studying this, we can see patterns in how elements behave.Dobereiner's Triads had limitations:
Not all elements known at that time could be classified into triads. Only four triads were identified by Dobereiner, leaving many elements unaccounted for.Newland’s octaves had limitations:
The classification of elements based on octaves was only successful up to calcium. The discovery of noble gases posed a challenge to Newland’s arrangement, as they did not fit into the periodic pattern without disrupting it completely.Advantages of Mendeleev’s Periodic table:
It accommodated newly discovered elements without disturbing the table's structure, including germanium, gallium, and scandium. Mendeleev’s table helped correct inaccurate atomic weights that were prevalent at the time. It introduced variations from the strict order of atomic weights.Limitations of Mendeleev’s Periodic table:
Hydrogen's position in the group of alkali metals contradicted its halogen-like qualities. Isotopes were not considered, leading to inconsistencies in the placement of elements like protium, deuterium, and tritium."The physical and chemical properties of elements are periodic functions of their atomic numbers."
Unlike atomic mass, which is influenced by the mass of protons and neutrons in the nucleus, the atomic number solely determines the number of electrons in an atom. Since chemical properties primarily depend on the arrangement of electrons in different energy levels, elements with different electronic configurations exhibit distinct chemical behaviors. Therefore, Moseley argued that atomic number, not atomic mass as proposed by Mendeleev, should be the basis for classifying elements in the periodic table. The periodic repetition of similar properties among elements grouped by their atomic numbers is known as periodicity. This concept highlights the predictable patterns in the chemical and physical properties of elements as their atomic numbers increase.Atomic and Ionic Radii:
Atomic Radii: The distance from the nucleus to the outermost electron shell defines atomic radii, which can be covalent, van der Waals, or metallic.
Covalent radii: Half the distance between nuclei of adjacent atoms in a single covalent bond.
Van der Waals radii: Half the internuclear distance between atoms of neighboring molecules in a solid.
Metallic radii: Half the distance between nuclei of adjacent atoms in a metallic crystal.
Atomic radii decrease across periods due to increased effective nuclear charge and increase down groups owing to additional electron shells and shielding effect.Ionic Radii: The effective distance from the nucleus to the electron cloud for ions formed from neutral atoms.
Ionic radii follow the same trend as atomic radii, decreasing across periods and increasing down groups.
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Concept Clarity: These notes provide a structured overview of the classification of elements and periodic trends, helping students understand fundamental concepts clearly.
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Exam Preparation: By studying these notes, students can also practice Important Questions for Class 11 Chemistry for their exams, as they cover the entire syllabus prescribed by the CBSE board.