NCERT Solutions for Class 9 Science Chapter 4 PDF
Protons: Positively charged particles found in the nucleus of the atom. Each proton has a relative mass of approximately 1 atomic mass unit (amu).
Neutrons: Neutrally charged particles also located in the nucleus. Neutrons have a mass similar to protons, approximately 1 amu, but they do not carry an electrical charge.
Electrons: Negatively charged particles that orbit the nucleus in specific energy levels or shells. Electrons have negligible mass compared to protons and neutrons.
1. What are the canal rays?
Solution: The radiations that are positively charged are canal rays. This discovery was crucial in the discovery of another subatomic particle that was positively charged – the proton.2. If an atom contains one electron and one proton, will it carry any charge or not?
Solution: Since a proton is a positively charged particle and an electron is a negatively charged particle, the net charge becomes neutral as both particles neutralise each other.1. On the basis of Thompson’s model of an atom, explain how the atom is neutral as a whole.
Solution: Thomson's model of the atom, proposed in the late 19th century, suggested the following: (i) An atom is envisioned as a uniform sphere filled with positive charge, with negatively charged electrons embedded within it like raisins in a pudding. (ii) According to Thomson's model, electrons and the positive charge are distributed uniformly throughout the atom, making the atom electrically neutral overall. This concept of equal positive and negative charges within the atom led to it being referred to as the "plum pudding model."2. On the basis of Rutherford’s model of an atom, which subatomic particle is present in the nucleus of an atom?
Solution:3. Draw a sketch of Bohr’s model of an atom with three shells.
Solution:4. What do you think would be the observation if the ∝– particle scattering experiment is carried out using a foil of a metal other than gold?
Solution: In the alpha particle scattering experiment, if any other metal foil is used instead of gold, the observations would generally remain consistent. This is because the fundamental structure of atoms, regardless of the element used, involves a dense nucleus surrounded by electrons in orbits or energy levels. Rutherford's experiment demonstrated that alpha particles, when directed at a thin foil of gold, sometimes bounced back or were deflected at large angles, indicating a concentrated positive charge (the nucleus) in the center of the atom. This basic atomic structure applies universally to all elements: a positively charged nucleus containing protons and neutrons, with electrons orbiting around it. Therefore, while the degree of scattering may vary depending on the atomic number and density of the foil used, the overall observation regarding the atom's structure would remain consistent across different metals.1. Name the three subatomic particles of an atom.
Solution: An atom consists of three subatomic particles:2. Helium atom has an atomic mass of 4 u and two protons in its nucleus. How many neutrons does it have?
Solution: Given: Atomic mass of helium atom = 4u, 2 protons in helium nucleus Atomic mass = number of protons + number of neutrons 4 = 2 + number of neutrons Number of neutrons = 4 – 2 = 2 Hence, Helium has 2 neutrons.1. Write the distribution of electrons in Carbon and Sodium atoms.
Solution:2. If the K and L shells of an atom are full, then what would be the total number of electrons in the atom?
Solution: K shell can hold 2 electrons. L shell can hold 8 electrons. Hence, when both the shells are full, the total number of electrons present in the atom = 2+8 = 10 electrons.1. How will you find the valency of chlorine, sulphur and magnesium?
Solution: Valency of an element refers to its tendency to gain, lose, or share electrons in order to achieve a stable electronic configuration, typically with a full outer shell. Mathematically, the valency can be determined based on the number of electrons in the outermost shell (also known as the valence shell):Valency of chlorine:
The electronic configuration of chlorine = 2, 8, 7 Chlorine has 7 (more than 4) electrons in its outermost shell. Therefore, the valency of chlorine = 8 – the number of electrons in the outermost shell = 8−7 = 1 Valency of Sulphur: The electronic configuration of Sulphur = 2, 8,6 Sulphur has 6 (more than 4) electrons in its outermost shell. Therefore, the valency of chlorine = 8 – the number of electrons in the outermost shell = 8−6 = 2 Valency of magnesium: The electronic configuration of Magnesium = 2, 8, 2 Magnesium has 2 (less than 4) electrons in its outermost shell. Therefore, the valency of magnesium= Number of electrons in its outermost shell = 21. If the number of electrons in an atom is 8 and the number of protons is also 8, then
(i) What is the atomic number of the atom? and
(ii) What is the charge on the atom?
Solution: Given: Number of electrons = 8 Number of protons = 8 (i) The atomic number of an atom is the same as the number of protons in that atom; hence, its atomic number is 8. (ii) In an atom, the number of protons is equal to the number of electrons. Hence, both the charges – positive and negative – neutralise each other. Therefore, the atom does not possess any charge.2. With the help of the given table, find out the mass number of oxygen and sulphur atom.
Table: Composition of Atoms of the First Eighteen Elements with Electron Distribution in Various Shells.
Name of Element | Symbol | Atomic number | Number of Protons | Number of Neutrons | Number of electrons | Distribution of electrons K L M N | Valency | |||
Hydrogen Helium Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon Sodium Magnesium | H He Li Be B C N O F Ne Na Mg | 1 2 3 4 5 6 7 8 9 10 11 12 | 1 2 3 4 5 6 7 8 9 10 11 12 | – 2 4 5 6 6 7 8 10 10 12 12 | 1 2 3 4 5 6 7 8 9 10 11 12 | 1 2 2 2 2 2 2 2 2 2 2 2 | – – 1 2 3 4 5 6 7 8 8 8 | – – – – – – – – – – 1 2 | – – – – – – – – – — – – | 1 0 1 2 3 4 3 2 1 0 1 2 |
Aluminium Silicon Phosphorus Sulphur Chlorine Argon | Al Si P S Cl Ar | 13 14 15 16 17 18 | 13 14 15 16 17 18 | 14 14 16 16 18 22 | 13 14 15 16 17 18 | 2 2 2 2 2 2 | 8 8 8 8 8 8 | 3 4 5 6 7 8 | – – – – – | 3 4 3,5 2 1 0 |
1. For the symbols H, D and T, tabulate three subatomic particles found in each of them.
Solution: The following table depicts the subatomic particles in Hydrogen (H), Deuterium (D), and Tritium(T).Isotope | Symbol | Mass no. | Atomic no. | No. of electrons | No. of protons | No. of neutrons |
Hydrogen | H | 1 | 1 | 1 | 1 | 0 |
Deuterium | D | 2 | 1 | 1 | 1 | 1 |
Tritium | T | 3 | 1 | 1 | 1 | 2 |
2. Write the electronic configuration of any one pair of isotopes and isobar.
Solution:(a) Isotopes: Isotopes are atoms of the same element that have the same number of protons (and therefore the same atomic number) but differ in the number of neutrons. This difference in neutrons results in isotopes having different mass numbers. Isotopes of an element behave similarly in chemical reactions because they have the same number of electrons and hence the same electronic configuration.
Example: Carbon has two major isotopes, Carbon-12 (6C12) and Carbon-14 (6C14). Both isotopes have the same atomic number (6) and thus the same number of protons and electrons, but Carbon-12 has 6 neutrons and Carbon-14 has 8 neutrons, leading to different mass numbers (12 and 14, respectively).(b) Isobars: Isobars are atoms of different elements that have the same mass number but different atomic numbers. Unlike isotopes, which are of the same element, isobars are different elements altogether. This means isobars have different numbers of protons and electrons and therefore different atomic numbers.
Example: Calcium-40 (20Ca40) and Argon-40 (18Ar40) are isobars because they both have a mass number of 40. Calcium-40 has an atomic number of 20 (20 protons), while Argon-40 has an atomic number of 18 (18 protons). Despite the different atomic numbers, they can have similar electron configurations in their respective shells due to having the same number of electrons (20 for Calcium-40 and 18 for Argon-40) in their neutral state.1. Compare the properties of electrons, protons and neutrons.
Solution:Property | Electrons | Protons | Neutrons |
Charge | Negatively charged | Positively charged | No charge. |
Location | Located outside the nucleus | Located within the nucleus | Located inside the nucleus of an atom |
Weight | Mass is negligible | 1 a.m.u | 1 a.m.u |
Affinity | Attracted towards positively charged | Attracted towards negatively charged | Do not get attracted to any charged particle |
2. What are the limitations of J.J.Thomson’s model of the atom?
Solution: The limitations of J.J. Thomson's model of the atom include:3. What are the limitations of Rutherford’s model of the atom?
Solution: The limitations of Rutherford's model of the atom include:4. Describe Bohr’s model of the atom.
Solution:5. Compare all the proposed models of an atom given in this chapter.
Solution:Thomson | Rutherford | Bohr |
● Sphere is positively charged. ● Electrons are negatively charged and scattered all through the inside of the sphere. ● Positively charged = negatively charged ● The net charge in the atom is zero. | ● The nucleus is at the centre and is positively charged, holding the entire mass. ● Electrons are negatively charged, revolving in a well-defined path ● In comparison with the nucleus, the size of the atom is very large. ● Force of attraction of the electrons towards the nucleus is balanced by centrifugal force acting away from it. As a result, electrons are not drawn close to the nucleus. | ● Nucleus is present at the centre and is positively charged ● Electrons are negatively charged, revolving around but do not radiate energy. ● The distinct orbits are labelled as K, L, M, and N |
6. Thomson’s Model of Atom.
7. Rutherford’s Model of Atoms.
8. Bohr’s model of the atom.
Summarise the rules for the writing of the distribution of electrons in various shells for the first eighteen elements.
Solution:9. Define valency by taking examples of silicon and oxygen.
Solution: Valency refers to the combining capacity of an atom, specifically how many electrons an atom needs to gain, lose, or share to achieve a stable electron configuration, typically with a full outer shell (octet rule).Example of Silicon (Atomic Number 14):
Example of Oxygen (Atomic Number 8):
10. Explain with examples
(i) Atomic number,
(ii) Mass number,
(iii) Isotopes and
(iv) Isobars.
Give any two uses of isotopes.
Solution: (i) The number of positively charged protons present in the nucleus of an atom is defined as the atomic number and is denoted by Z. Example: Hydrogen has one proton in its nucleus; hence, its atomic number is one. (ii) The total number of protons and neutrons present in the nucleus of an atom is known as the mass number. It is denoted by A. 20 Ca 40 . The mass number is 40. The atomic number is 20. (iii) The atoms which have the same number of protons but a different number of neutrons are referred to as isotopes. Hence, the mass number varies. Example: The most simple example is the Carbon molecule which exists as 6 C 12 and 6 C 14 (iv) Isobars: Isobars are atoms which have the same mass number but differ in atomic number. Examples are, 20 Ca 40 and 18 Ar 40 Uses of isotopes11. Na+ has completely filled K and L shells. Explain.
Solution: Sodium (Na) has an atomic number of 11, which means it has 11 electrons.12. If the bromine atom is available in the form of, say, two isotopes 35 Br 79 (49.7%) and 35 Br 81 (50.3%), calculate the average atomic mass of the Bromine atom.
Solution: The atomic mass of an element is the mass of one atom of that element. Average atomic mass takes into account the isotopic abundance. Isotope of bromine with atomic mass 79 u = 49.7% Therefore, Contribution of 35 Br 79 to atomic mass = (79 × 49.7)/100 ⇒ 39.26 u Isotope of bromine with atomic mass 81 u = 50.3% Contribution of 35 Br 81 to the atomic mass of bromine = (81 × 50.3)/100⇒ 40.64u
Hence, the average atomic mass of the bromine atom = 39.26 + 40.64 u = 79.9u13. The average atomic mass of a sample of element X is 16.2 u. What are the percentages of isotopes 8 X 16 and 8 X 18 in the sample?
Solution: Let the percentage of 8 X 16 be ‘a’ and that of 8 X 18 be ‘100-a’. As per the given data, 16.2u = 16 a / 100 + 18 (100-a) /100 1620 = 16a + 1800 – 18a 1620 = 1800 – 2a a = 90% Hence, the percentage of the isotope in the sample 8 X 16 is 90% and that of 8 X 18 = 100-a = 100- 90=10%14. If Z=3, what would be the valency of the element? Also, name the element.
Solution: Given: Atomic number, Z = 3 The electronic configuration of the element = K-2; L-1, hence its valency = 1 The element with atomic number 3 is Lithium.15. Composition of the nuclei of two atomic species, X and Y, are given as under
X Y
Protons = 6 6
Neutrons = 6 8
Give the mass numbers of X and Y. What is the relation between the two species?
Solution: Mass number of X: Protons + neutrons = 6+6 = 12 Mass number of Y: Protons + neutrons = 6+8 = 14 They are the same element, and their atomic numbers are the same. They are isotopes, as they differ in the number of neutrons and hence their mass numbers.16. For the following statements, write T for true and F for false.
(a) J.J. Thomson proposed that the nucleus of an atom contains only nucleons. (b) A neutron is formed by an electron and a proton combining together. Therefore, it is neutral. (c) The mass of an electron is about 1/2000 times that of a proton. (d) An isotope of iodine is used for making tincture iodine, which is used as a medicine. Solution: (a) The statement is False. (b) The statement is False. (c) The statement is True. (d) The statement is False.17. Put a tick(✓) against the correct choice and cross(x) against the wrong choice in questions 15, 16 and 17.
Rutherford’s alpha–particle scattering experiment was responsible for the discovery of
(a) Atomic nucleus (b) Electron (c) Proton (d) Neutron Solution: (a) Atomic nucleusIsotopes of an element have
(a) The same physical properties (b) Different chemical properties (c) Different number of neutrons (d) Different atomic numbers Solution: (c) Different number of neutrons18. Number of valence electrons in Cl – ion are
(a) 16 (b) 8 (c) 17 (d) 18 Solution: (b) 8 The electronic distribution of Cl is K-2, L-8, M-7. Valence electrons are 7; hence, chlorine gains one electron for the formation of Cl – . Therefore, its valency is 8.19. Which one of the following is a correct electronic configuration of Sodium?
(a) 2, 8 (b) 8, 2, 1 (c) 2, 1, 8 (d) 2, 8, 1 Solution: (d) 2, 8, 1Complete the following table.
Atomic Number | Mass Number | Number of Neutrons | Number of Protons | Number of Electrons | Name of the Atomic Species |
9 16 – – – | – 32 24 2 1 | 10 – – – 0 | – – 12 1 1 | – – – – 0 | – Sulphur – – – |
Atomic Number | Mass Number | Number of Neutrons | Number of Protons | Number of Electrons | Name of the Atomic Species |
9 16 12 1 1 | 19 32 24 2 1 | 10 16 12 1 0 | 9 16 12 1 1 | 9 16 12 1 0 | Fluorine Sulphur Magnesium Deuterium Hydrogen |