Condensation occurs when water vapor(gaseous phase) is subjected to low temperature (cooling) or high pressure (compression), and it gets converted into water(liquid phase). This change in state from gas to liquid triggers the pouring of rain from clouds. As the clouds rise higher, the temperature drops below the due point, and pressure increases due to the mixing of more vapor in the clouds. These conditions force the vapor in clouds to condense and fall down as rainwater resulting in precipitation.
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△Hvap=−△Hcond
Where, △Hvap is the enthalpy of vaporization and △Hcond is the enthalpy of condensation. Enthalpy of Vaporization is the amount of heat that must be added to transform a liquid into a gas and Enthalpy of Condensation is the amount of heat that is released by a gas when it is converted to liquid. As evident from the above equation, the enthalpy of vaporization is positive because heat is absorbed or gained from the system and the enthalpy of condensation is negative because heat is released or lost to the system. Based on this, we can equate the condensation of water vapor into the water chemically asH2O(g) ⇌ H2O(l)