The formula for carbon monoxide is CO, and it is widely used in the production of both organic and inorganic compounds. Due to its flammable and toxic nature, strict precautions must be taken when handling it. It was Greek philosopher Aristotle who first noted that burning coal results in the formation of carbon monoxide. In 1776, French Chemist de Lassone successfully created this compound by heating zinc oxide (ZnO) with coke. Initially, he mistakenly identified it as hydrogen due to its blue flame when burning. However, further research by Scottish Chemist William Cruickshank in 1800 revealed that it is a combination of carbon and oxygen rather than hydrogen.
Carbon monoxide and hemoglobin have a strong combination affinity, making it a very dangerous gas. When carbon monoxide concentrations increase in living beings, oxygen deprivation results in dizziness, unconsciousness, and even death. The gas is highly flammable and poisonous and has been reported in many cases.
There is no taste to carbon monoxide, which is colorless, odorless, and produced as a byproduct of incomplete combustion of carbon compounds, mainly in internal combustion engines. In spite of its serious and harmful toxicity, it is extremely valuable and underpins many modern technologies. The fuel burns in the air with a characteristic blue flame giving carbon dioxide.
Despite its highly poisonous properties, carbon monoxide has a wide range of flammability in the air. It becomes a liquid at -191.53 degrees Celsius and is insoluble in water above 70 degrees Celsius.
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As part of a carbon monoxide molecule, two pi and one sigma bonds connect each carbon atom and oxygen atom. One carbon monoxide molecule contains four valence electrons and six oxygen valence electrons, totaling ten electrons in the valence shell. As a result, both atoms form triple bonds using the octet rule. Carbon monoxide exhibits sp hybridization. Bond angles are 180°. Bond lengths are 112.8 pm. Carbon monoxide comprises one oxygen atom and one carbon atom bonded by a triple bond consisting of two covalent bonds and one dative covalent bond.
Formula | CO |
Molar Mass | 28.01 g/mol |
Density | 1.14 kg/m³ |
Melting Point | -205 °C |
Boiling Point | -191.5 °C |
It is clear from the carbon monoxide symbol that carbon monoxide is the most basic oxocarbon. It has several chemical names, including carbon oxide, carbon protoxide, carbon (II) oxide, etc. There is a single carbon atom and one oxygen atom (a common property in every monoxide formula). There are three bonds in between the carbon and oxygen atoms. There are two pi bonds and one sigma bond. The bond length between the carbon and oxygen atoms is 112.8 pm.
Due to its structure, carbon monoxide shares characteristics with other diatomic species with triple bonds, such as molecular nitrogen. These similarities can be observed in the bond length - nitrogen has a bond length of 109.76 pm, which is comparable to carbon monoxide. Additionally, their molecular masses are nearly identical. Furthermore, their boiling points and melting points are nearby; carbon monoxide boils at 82 K and melts at 68 K while nitrogen molecules have boiling and melting points of 77K and 63 K, respectively. A similar pattern can be seen in their bond dissociation energy - carbon monoxide has a higher bond dissociation energy of 1072 kJ/mol compared to nitrogen's 942 kJ/mol value.
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CO (carbon monoxide symbol) is readily found in natural and artificial settings, typically measured in parts per million. The primary industrial source of carbon monoxide is producer gas, a mixture primarily composed of carbon monoxide and nitrogen generated through coal combustion at high temperatures. This can be easily understood by examining the chemical formula for carbon monoxide. During this process, air is passed through coke, a fuel with a high carbon content, producing carbon dioxide. The hot carbon then reaches an equilibrium state with the remaining carbon to create carbon monoxide through a reaction known as the Boudouard reaction. The equation for this reaction is given below:
CO2 + C → 2CO.
Similarly, water gas is another source for the production of carbon monoxide. In this reaction, steam reacts with carbon endothermically and produces carbon monoxide and hydrogen as a result. This reaction produces carbon monoxide and hydrogen. The equation for carbon monoxide given above is shown below.
H2O + C → H2 + CO.
Carbon monoxide can also be produced by synthesis gases usually obtained from natural gas and other fuel sources.
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The use of carbon monoxide in industrial settings involves creating synthetic chemicals and utilizing it in metallurgical processes. However, its global impact is concerning due to its role in contributing to climate change. This gas is already a prominent air pollutant caused by both vehicular emissions and various industrial activities. While it can serve as an endogenous neurotransmitter at low levels, high concentrations can result in biological toxicity and potential poisoning.
A particular niche use of carbon monoxide that is thought of is its use as a fuel on Mars. Due to the carbon dioxide present in Mars's atmosphere, oxygen and carbon monoxide can be easily generated as fuels for surface transportation. Furthermore, this is unique because it will not use Martian water resources to generate hydrogen-based fuel.