NCERT Solutions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers
NCERT Solutions for Class 12 Chemistry Chapter 11 contains all the questions with detailed solutions. Students are advised to solve these questions for better understanding of the concepts in Chapter 11.
Krati Saraswat29 Feb, 2024
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NCERT Solutions for Class 12 Chemistry Chapter 11 Alcohols, Phenols and Ethers is prepared by our senior and renowned teachers of Physics Wallah primary focus while solving these questions of class-12 in NCERT textbook, also do read theory of this Chapter 11 Alcohols, Phenols and Ethers while going before solving the NCERT questions. Our Physics Wallah team Prepared Other Subjects NCERT Solutions for class 12.
NCERT Solutions For Class 12 Chemistry Chapter 1
NCERT Solutions for Class 12 Chemistry Chapter 11 Overview
NCERT Solutions for Class 12 Chemistry Chapter 11 covers several important topics. It is highly recommended that students to review each topic thoroughly to gain a comprehensive understanding of the concepts taught in the chapter and make optimal use of the provided solutions. These solutions are the result of dedicated efforts by the Physics Wallah teachers aimed at assisting students in grasping the concepts covered in this chapter. By going through and practising these solutions, the objective is for students to achieve excellent results in their exams effortlessly.NCERT Solutions for Class 12 Chemistry Chapter 11
Answer the following Questions of NCERT Solutions for Class 12 Chemistry Chapter 11:
Question 1. Write IUPAC names of the following compounds: (i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)
(ix)
(x)
(xi)
(xii)
Solution :
(i) 2, 2, 4-Trimethylpentan-3-ol
(ii) 5-Ethylheptane-2, 4-diol
(iii) Butane-2, 3-diol
(iv) Propane-1, 2, 3-triol
(v) 2-Methylphenol
(vi) 4-Methylphenol
(vii) 2, 5-Dimethylphenol
(viii) 2, 6-Dimethylphenol
(ix) 1-Methoxy-2-methylpropane
(x) Ethoxybenzene
(xi) 1-Phenoxyheptane
(xii) 2-Ethoxybutane
NCERT Solutions For Class 12 Chemistry Chapter 2
Question 2. Write structures of the compounds whose IUPAC names are as follows: (i) 2-Methylbutan-2-ol (ii) 1-Phenylpropan-2-ol (iii) 3,5-Dimethylhexane −1, 3, 5-triol (iv) 2,3 − Diethylphenol (v) 1 − Ethoxypropane (vi) 2-Ethoxy-3-methylpentane (vii) Cyclohexylmethanol (viii) 3-Cyclohexylpentan-3-ol (ix) Cyclopent-3-en-1-ol (x) 3-Chloromethylpentan-1-ol. Solution : (i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)
(ix)
(x)
NCERT Solutions For Class 12 Chemistry Chapter 3
Question 3. (i) Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names. (ii) Classify the isomers of alcohols in 3 (i) as primary, secondary and tertiary alcohols. Solution : (i) The structures of all isomeric alcohols of molecular formula, C5H12O are shown below: (a)
Pentan-1-ol (1°)
(b)
2-Methylbutan-1-ol (1°)
(c)
3-Methylbutan-1-ol (1°)
(d)
2, 2-Dimethylpropan-1-ol (1°)
(e)
Pentan-2-ol (2°)
(f)
3-Methylbutan-2-ol (2°)
(g)
Pentan-3-ol (2°)
(h)
2-Methylbutan-2-ol (3°)
(ii) Primary alcohol: Pentan-1-ol; 2-Methylbutan-1-ol;
3-Methylbutan-1-ol; 2, 2−Dimethylpropan-1-ol
Secondary alcohol: Pentan-2-ol; 3-Methylbutan-2-ol;
Pentan-3-ol
Tertiary alcohol: 2-methylbutan-2-ol
NCERT Solutions For Class 12 Chemistry Chapter 4
Question 4. Explain why propanol has higher boiling point than that of the hydrocarbon, butane? Solution : Propanol undergoes intermolecular H-bonding because of the presence of −OH group. On the other hand, butane does not
Therefore, extra energy is required to break hydrogen bonds. For this reason, propanol has a higher boiling point than hydrocarbon butane.
NCERT Solutions For Class 12 Chemistry Chapter 5
Question 5. Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular masses. Explain this fact. Solution : Alcohols form H-bonds with water due to the presence of −OH group. However, hydrocarbons cannot form H-bonds with water.
As a result, alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular masses.
Question
6. What is meant by hydroboration-oxidation reaction? Illustrate it with an example.
Solution :
The addition of borane followed by oxidation is known as the hydroboration-oxidation reaction. For example, propan-1-ol is produced by the hydroboration-oxidation reaction of propene. In this reaction, propene reacts with diborane (BH3)2 to form trialkyl borane as an addition product. This addition product is oxidized to alcohol by hydrogen peroxide in the presence of aqueous sodium hydroxide.
NCERT Solutions For Class 12 Chemistry Chapter 6
Question 7. Give the structures and IUPAC names of monohydric phenols of molecular formula, C7H8O. Solution :
Question
8. While separating a mixture of ortho and para nitrophenols by steam distillation, name the isomer which will be steam volatile. Give reason.
Solution :
Intramolecular H-bonding is present in o-nitrophenol. In p-nitrophenol, the molecules are strongly associated due to the presence of intermolecular bonding. Hence, o-nitrophenol is steam volatile.
Question
9. Give the equations of reactions for the preparation of phenol from cumene.
Solution :
To prepare phenol, cumene is first oxidized in the presence of air of cumene hydro-peroxide.
Then, cumene hydroxide is treated with dilute acid to prepare phenol and acetone as by-products.
NCERT Solutions For Class 12 Chemistry Chapter 7
Question 10. Write chemical reaction for the preparation of phenol from chlorobenzene. Solution : Chlorobenzene is fused with NaOH (at 623 K and 320 atm pressure) to produce sodium phenoxide, which gives phenol on acidification.
Question
11. Write the mechanism of hydration of ethene to yield ethanol.
Solution :
The mechanism of hydration of ethene to form ethanol involves three steps.
Step 1:
Protonation of ethene to form carbocation by electrophilic attack of H3O+:
Step 2:
Nucleophilic attack of water on carbocation:
Step 3:
Deprotonation to form ethanol:
NCERT Solutions For Class 12 Chemistry Chapter 8
Question 12. You are given benzene, conc. H2SO4 and NaOH. Write the equations for the preparation of phenol using these reagents. Solution :
Question
13. Show how will you synthesize:
(i) 1-phenylethanol from a suitable alkene.
(ii) cyclohexylmethanol using an alkyl halide by an SN2 reaction.
(iii) pentan-1-ol using a suitable alkyl halide?
Solution :
(i) By acid-catalyzed hydration of ethylbenzene (styrene), 1-phenylethanol can be synthesized.
(ii) When chloromethylcyclohexane is treated with sodium hydroxide, cyclohexylmethanol is obtained.
(iii) When 1-chloropentane is treated with NaOH, pentan-1-ol is produced.
NCERT Solutions For Class 12 Chemistry Chapter 9
Question 14. Give two reactions that show the acidic nature of phenol. Compare acidity of phenol with that of ethanol. Solution : The acidic nature of phenol can be represented by the following two reactions: (i) Phenol reacts with sodium to give sodium phenoxide, liberating H2.
(ii) Phenol reacts with sodium hydroxide to give sodium phenoxide and water as by-products.
The acidity of phenol is more than that of ethanol. This is because after losing a proton, the phenoxide ion undergoes resonance and gets stabilized whereas ethoxide ion does not.
NCERT Solutions For Class 12 Chemistry Chapter 10
Question 15. Explain why is ortho nitrophenol more acidic than ortho methoxyphenol? Solution :
The nitro-group is an electron-withdrawing group. The presence of this group in the ortho position decreases the electron density in the O−H bond. As a result, it is easier to lose a proton. Also, the o-nitrophenoxide ion formed after the loss of protons is stabilized by resonance. Hence, ortho nitrophenol is a stronger acid.
On the other hand, methoxy group is an electron-releasing group. Thus, it increases the electron density in the O−H bond and hence, the proton cannot be given out easily.
For this reason, ortho-nitrophenol is more acidic than ortho-methoxyphenol.
Question
16. Explain how does the −OH group attached to a carbon of benzene ring activate it towards electrophilic substitution?
Solution :
The −OH group is an electron-donating group. Thus, it increases the electron density in the benzene ring as shown in the given resonance structure of phenol.
As a result, the benzene ring is activated towards electrophilic substitution.
Question
17. Give equations of the following reactions:
(i) Oxidation of propan-1-ol with alkaline KMnO4 solution.
(ii) Bromine in CS2 with phenol.
(iii) Dilute HNO3 with phenol.
(iv) Treating phenol with chloroform in presence of aqueous NaOH.
Solution :
(i)
(ii)
(iii)
(iv)
Question
18. Explain the following with an example.
(i) Kolbe’s reaction.
(ii) Reimer-Tiemann reaction.
(iii) Williamson ether synthesis.
(iv) Unsymmetrical ether.
Solution :
(i) Kolbe’s reaction:
When phenol is treated with sodium hydroxide, sodium phenoxide is produced. This sodium phenoxide when treated with carbon dioxide, followed by acidification, undergoes electrophilic substitution to give ortho-hydroxybenzoic acid as the main product. This reaction is known as Kolbe’s reaction.
(ii) Reimer-Tiemann reaction:
When phenol is treated with chloroform (CHCl3) in the presence of sodium hydroxide, a −CHO group is introduced at the ortho position of the benzene ring.
This reaction is known as the Reimer-Tiemann reaction.
The intermediate is hydrolyzed in the presence of alkalis to produce salicyclaldehyde.
(iii) Williamson ether synthesis:
Williamson ether synthesis is a laboratory method to prepare symmetrical and unsymmetrical ethers by allowing alkyl halides to react with sodium alkoxides.
This reaction involves SN2 attack of the alkoxide ion on the alkyl halide. Better results are obtained in case of primary alkyl halides.
If the alkyl halide is secondary or tertiary, then elimination competes over substitution.
(iv) Unsymmetrical ether:
An unsymmetrical ether is an ether where two groups on the two sides of an oxygen atom differ (i.e., have an unequal number of carbon atoms). For example: ethyl methyl ether (CH3−O−CH2CH3).
Question
19. Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene.
Solution :
The mechanism of acid dehydration of ethanol to yield ethene involves the following three steps:
Step 1:
Protonation of ethanol to form ethyl oxonium ion:
Step 2:
Formation of carbocation (rate determining step):
Step 3:
Elimination of a proton to form ethene:
The acid consumed in step 1 is released in Step 3. After the formation of ethene, it is removed to shift the equilibrium in a forward direction.
Question
20. How are the following conversions carried out?
(i) Propene → Propan-2-ol
(ii) Benzyl chloride → Benzyl alcohol
(iii) Ethyl magnesium chloride → Propan-1-ol.
(iv) Methyl magnesium bromide → 2-Methylpropan-2-ol.
Solution :
(i) If propene is allowed to react with water in the presence of an acid as a catalyst, then propan-2-ol is obtained.
(ii) If benzyl chloride is treated with NaOH (followed by acidification) then benzyl alcohol is produced.
(iii) When ethyl magnesium chloride is treated with methanal, an adduct is the produced which gives propan-1-ol on hydrolysis.
(iv) When methyl magnesium bromide is treated with propane, an adduct is the product which gives 2-methylpropane-2-ol on hydrolysis.
Question
21. Name the reagents used in the following reactions:
(i) Oxidation of a primary alcohol to carboxylic acid.
(ii) Oxidation of a primary alcohol to aldehyde.
(iii) Bromination of phenol to 2,4,6-tribromophenol.
(iv) Benzyl alcohol to benzoic acid.
(v) Dehydration of propan-2-ol to propene.
(vi) Butan-2-one to butan-2-ol.
Solution :
(i) Acidified potassium permanganate
(ii) Pyridinium chlorochromate (PCC)
(iii) Bromine water
(iv) Acidified potassium permanganate
(v) 85% phosphoric acid
(vi) NaBH4 or LiAlH4
Question
22. Give reason for the higher boiling point of ethanol in comparison to methoxymethane.
Solution :
Ethanol undergoes intermolecular H-bonding due to the presence of −OH group, resulting in the association of molecules. Extra energy is required to break these hydrogen bonds. On the other hand, methoxymethane does not undergo H-bonding. Hence, the boiling point of ethanol is higher than that of methoxymethane.
Question
23. Give IUPAC names of the following ethers:
(i)
(ii)
(iii)
(iv)
(v)
(vi)
Solution :
(i) 1-Ethoxy-2-methylpropane
(ii) 2-Chloro-1-methoxyethane
(iii) 4-Nitroanisole
(iv) 1-Methoxypropane
(v) 1-Ethoxy-4, 4-dimethylcyclohexane
(vi) Ethoxybenzene
Question
24. Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis:
(i) 1-Propoxypropane
(ii) Ethoxybenzene
(iii) 2-Methoxy-2-methylpropane
(iv) 1-Methoxyethane
Solution :
(i)
(ii)
(iii)
(iv)
Question
25. Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers.
Solution :
The reaction of Williamson synthesis involves SN2 attack of an alkoxide ion on a primary alkyl halide.
But if secondary or tertiary alkyl halides are taken in place of primary alkyl halides, then elimination would compete over substitution. As a result, alkenes would be produced. This is because alkoxides are nucleophiles as well as strong bases. Hence, they react with alkyl halides, which results in an elimination reaction.
Question
26. How is 1-propoxypropane synthesised from propan-1-ol? Write mechanism of this reaction.
Solution :
1-propoxypropane can be synthesized from propan-1-ol by dehydration.
Propan-1-ol undergoes dehydration in the presence of protic acids (such as H2SO4, H3PO4) to give 1-propoxypropane.
The mechanism of this reaction involves the following three steps:
Step 1:
Protonation
Step 2:
Nucleophilic attack
Step 3:
Deprotonation
Question
27. Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method. Give reason.
Solution :
The formation of ethers by dehydration of alcohol is a bimolecular reaction (SN2) involving the attack of an alcohol molecule on a protonated alcohol molecule. In the method, the alkyl group should be unhindered. In case of secondary or tertiary alcohols, the alkyl group is hindered. As a result, elimination dominates substitution. Hence, in place of ethers, alkenes are formed.
Question
28. Write the equation of the reaction of hydrogen iodide with:
(i) 1-propoxypropane
(ii) Methoxybenzene and
(iii) Benzyl ethyl ether
Solution :
(i)
(ii)
(iii)
Question
29. Explain the fact that in aryl alkyl ethers
(i) The alkoxy group activates the benzene ring towards electrophilic substitution and
(ii) It directs the incoming substituents to ortho and para positions in benzene ring.
Solution :
(i)
In aryl alkyl ethers, due to the +R effect of the alkoxy group, the electron density in the benzene ring increases as shown in the following resonance structure.
Thus, benzene is activated towards electrophilic substitution by the alkoxy group.
(ii) It can also be observed from the resonance structures that the electron density increases more at the ortho and para positions than at the meta position. As a result, the incoming substituents are directed to the ortho and para positions in the benzene ring.
Question
30. Write the mechanism of the reaction of HI with methoxymethane.
Solution :
The mechanism of the reaction of HI with methoxymethane involves the following steps:
Step1:
Protonation of methoxymethane:
Step2:
Nucleophilic attack of I−:
Step3:
When HI is in excess and the reaction is carried out at a high temperature, the methanol formed in the second step reacts with another HI molecule and gets converted to methyl iodide
Question
31. Write equations of the following reactions:
(i) Friedel-Crafts reaction−alkylation of anisole.
(ii) Nitration of anisole.
(iii) Bromination of anisole in ethanoic acid medium.
(iv) Friedel-Craft’s acetylation of anisole.
Solution :
(i)
(ii)
(iii)
(iv)
Question
32. Show how would you synthesise the following alcohols from appropriate alkenes?
(i)
(ii)
(iii)
(iv)
Solution :
The given alcohols can be synthesized by applying Markovnikov’s rule of acid-catalyzed hydration of appropriate alkenes.
(i)
(ii)
(iii)
Acid-catalyzed hydration of pent-2-ene also produces pentan-2-ol but along with pentan-3-ol.
Thus, the first reaction is preferred over the second one to get pentan-2-ol.
(iv)
Question
33. When 3-methylbutan-2-ol is treated with HBr, the following reaction takes place:
Give a mechanism for this reaction.
(Hint : The secondary carbocation formed in step II rearranges to a more
stable tertiary carbocation by a hydride ion shift from 3rd carbon atom.
Solution :
The mechanism of the given reaction involves the following steps:
Step 1:
Protonation
Step 2:
Formation of 2° carbocation by the elimination of a water molecule
Step 3:
Re-arrangement by the hydride-ion shift
Step 4:
Nucleophilic attack
Question
34. Classify the following as primary, secondary and tertiary alcohols:
(i)
(ii)
(iii)
(iv)
(v)
(vi)
Solution :
Primary alcohol → (i), (ii), (iii)
Secondary alcohol → (iv), (v)
Tertiary alcohol → (vi)
Question
35. Identify allylic alcohols in the above examples.
Solution :
The alcohols given in (ii) and (vi) are allylic alcohols.
Question
36. Name the following compounds according to IUPAC system.
(i)
(ii)
(iii)
(iv)
(v)
Solution :
(i) 3-Chloromethyl-2-isopropylpentan-1-ol
(ii) 2, 5-Dimethylhexane-1, 3-diol
(iii) 3-Bromocyclohexanol
(iv) Hex-1-en-3-ol
(v) 2-Bromo-3-methylbut-2-en-1-ol
Question
37. Show how are the following alcohols prepared by the reaction of a suitable Grignard reagent on methanal?
(i)
(ii)
Solution :
(i)
(ii)
Question
38. Write structures of the products of the following reactions:
(i)
(ii)
(iii)
Solution :
(i)
(ii)
(iii)
Question
39. Give structures of the products you would expect when each of the following alcohol reacts with (a) HCl-ZnCl2 (b) HBr and (c) SOCl2.
(i) Butan-1-ol
(ii) 2-Methylbutan-2-ol
Solution :
(a)
(i)
Primary alcohols do not react appreciably with Lucas’ reagent (HCl-ZnCl2) at room temperature.
(ii)
Tertiary alcohols react immediately with Lucas’ reagent.
(b)
(i)
(ii)
(c)
(i)
(ii)
Question
40. Predict the major product of acid catalysed dehydration of
(i) 1-Methylcyclohexanol and
(ii) Butan-1-ol
Solution :
(i)
(ii)
Question
41. Ortho and para nitrophenols are more acidic than phenol. Draw the resonance structures of the corresponding phenoxide ions.
Solution :
Resonance structure of the phenoxide ion
Resonance structures of p-nitrophenoxide ion
Resonance structures of o-nitrophenoxide ion
It can be observed that the presence of nitro groups increases the stability of phenoxide ion.
Question
42. Write the equations involved in the following reactions:
(i) Reimer-Tiemann reaction
(ii) Kolbe’s reaction
Solution :
1.Reimer-Tiemann reaction
2.Kolbe’s reaction
Question
43. Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.
Solution :
In Williamson synthesis, an alkyl halide reacts with an alkoxide ion. Also, it is an SN2 reaction. In the reaction, alkyl halides should be primary having the least steric hindrance. Hence, an alkyl halide is obtained from ethanol and alkoxide ion from 3-methylpentan-2-ol.
Question
44. Which of the following is an appropriate set of reactants for the preparation of 1-methoxy-4-nitrobenzene and why?
(i)
(ii)
Solution :
Set (ii) is an appropriate set of reactants for the preparation of 1-methoxy-4-nitrobenzene.
In set (i), sodium methoxide (CH3ONa) is a strong nucleophile as well as a strong base. Hence, an elimination reaction predominates over a substitution reaction.
Question
45. Predict the products of the following reactions:
(i)
(ii)
(iii)
(iv)
Solution :
(i)
(ii)
(iii)
(iv)
NCERT Solutions for Class 12 Chemistry Chapter 11 FAQs
Which chapter of Class 12 chemistry is most important?
Organic chemistry is the most important topic for CBSE Class 12 Chemistry exam.
Is 12th chemistry hard?
Believe me, chemistry is one of the easiest subjects in the science stream provided you study it with full concentration and consistently.
Is 12th chemistry exam easy?
The difficulty level of the CBSE Class 12 Chemistry questions ranged from easy to moderate.
Talk to a counsellorHave doubts? Our support team will be happy to assist you!
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