Monoatomic Ions and Polyatomic Ions

Atom and Molecule of Class 9

Monoatomic ions : Those ions which are formed form single atoms are called monoatomic ions or simple ions.

e.g.  Na+, Mg2+ etc.

Polyatomic ion 

Ions formed from a group of atoms carrying a charge (either negative or positive) are known as a polyatomic ion or compound ion.

For example .

IONIC COMPOUNDS

Those compounds which are made up of ions (cations and anions) and are held together by strong electrostatic forces of attraction are called ionic compounds.

The forces which hold the ions together in an ionic compound are known as ionic bonds or electrovalent bonds.

e.g. Calcium nitrate Ca(NO3)2 is an ionic compound, whose one molecule is made up of one calcium ion (Ca2+) and two nitrate ions (NO3), making the overall charge on calcium nitrate zero.

Overall charge on an ionic compound is always zero

Some of the common ionic compound, their formula and the ions present in them are given below :

Some Ionic compounds 

Name

Formula

Ions present

1. sodium chloride

NaCl

Na+ and Cl

2. Potassium chloride

KCl

K+ and Cl

3. Ammonium chloride

NH4Cl

NH4+ and Cl

4. Magnesium 

MgCl2

Mg2+ and Cl

5. Calcium chloride

CaCl2

Ca2+ and Cl

6. Magnesium oxide

MgO

Mg2+ and O2

7. Calcium oxide

CaO

Ca2+ and O2

8. Aluminium oxide

Al2O3

Al3+ and O2

9. Sodium hydroxide

NaOH

Na+ and OH

10. Copper sulphate

CuSO4

Cu2+ and SO

11. Calcium nitrate

Ca(NO2)2

Ca2+ and NO3

As discussed earlier a compound is always made up of the same elements combined together in a fixed proportion by mass. For example Hydrogen chloride contains hydrogen and chlorine in a fixed ratio of 1 : 35.5 by mass. Similarly calcium oxide contains calcium and oxygen in the fixed ratio of 40 : 16 or 5 : 2 by mass.

Some ionic compounds

Ionic Compound

Constituting Elements

Ratio by Mass

Calcium oxide

Magnesium 

Sulphide

Sodium chloride

Calcium and oxygen

Magnesium and sulphur

Sodium and chlorine

5:2

3:4

23:35:5

Formula Unit of Ionic Compounds :

The simplest combination of ions that produces and electrically neutral unit,  is called  a formula unit of the ionic compound. Molecular formula of ionic compounds cannot be determined because they consist of large no. of ions. So, ionic compounds are represented by formula unit.

e.g. Sodium chloride is an ionic compound which consists of a large number of Na+ and Cl- ions (but they should be equal in number). So, the actual formula of sodium chloride should be (Na+)n(Cl-)n or (Na+Cl-)n, where ‘n’ is a large number. Nacl is the simplest formula of sodium chloride and thus, the formula unit of sodium chloride is NaCl.

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