Colloids

Surface Chemistry of Class 12

An ordinary solution consists of a solvent and a solute. The particles of a solute in an ordinary solution are usually either normal molecules or ions. In some solution the particles of solute are much larger: they may consist of aggregates of hundreds of ordinary sized molecules or even of a single larger or macro-molecule. Such as proteins dissolved in water. Such kind of solution is referred to as colloidal solution.

A colloidal solution cannot always be distinguished from a true solution with the naked eye. The particles, even though they may consist of some thousands of molecules, will pass through a filter paper, and cannot be seen under the microscope. A colloidal solution, however, is a two-phase system, whereas a true solution is regarded as being homogeneous, and therefore consists of only one phase. Colloidal are intermediate between solutions and precipitates, and there is a gradual transition between the two.

In gist, a colloidal solution is a heterogeneous two−phase system in which a substance is distributed in colloid state (i.e., of diameter between 2 x 10-4 to 1 x 10-7 cm) in an insoluble medium. The particle of the dispersed substance are in discontinuous phase called dispersed phase; while insoluble medium or external phase in which they are distributed is called dispersion medium. Besides these, a colloidal solution some times have a stabilizing agent which keeps the colloidal particles apart, thereby avoiding their coalescence and consequent settling under the influence of gravity.

Types of Colloids

Dispersed phase

Dispersion medium

Name of Colloidal form

Some examples

1. Gas

Liquid

Foam or froth

Foam, whipped cream, beaten egg whites, froth, lemonade, soap sol, detergent solution etc.

2. Gas

Solid

Solid foam

Pumic stone (air in silicates) floating, soaps, rubber, biscuit, cake, breads dough, lava, volcanic ash, styrene foam, etc.

3. Liquid

Gas

Liquid aerosols

mist, fog, clouds, insecticide spray etc.

4. Liquid

Liquid

Emulsions

Milk, emulsified oils, medicine, cream, mayonnaise, etc.

5. Liquid

Solid

Gels

Cheese, jellies, gel, curd, butter, boot polish, pearl (CaCO3 with water inclusions), etc.

6. Solid

Gas

Solid aerosols

Smoke, dust storm, fume, etc.

7. Solid

Liquid

Sols

Glue, Indian ink, some paints, starch dispersed in water, milk of magnesia, gold sol, sols of As2O3, S, Fe2O3 and AgCl in water, Fe(OH)3 sol, white of an egg etc.

8. Solid

Solid

Solid sols

Black diamond, ruby glass, some alloys and minerals, and synthetic gem, etc.

 

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