Colloids
Surface Chemistry of Class 12
An ordinary solution consists of a solvent and a solute. The particles of a solute in an ordinary solution are usually either normal molecules or ions. In some solution the particles of solute are much larger: they may consist of aggregates of hundreds of ordinary sized molecules or even of a single larger or macro-molecule. Such as proteins dissolved in water. Such kind of solution is referred to as colloidal solution.
A colloidal solution cannot always be distinguished from a true solution with the naked eye. The particles, even though they may consist of some thousands of molecules, will pass through a filter paper, and cannot be seen under the microscope. A colloidal solution, however, is a two-phase system, whereas a true solution is regarded as being homogeneous, and therefore consists of only one phase. Colloidal are intermediate between solutions and precipitates, and there is a gradual transition between the two.
In gist, a colloidal solution is a heterogeneous two−phase system in which a substance is distributed in colloid state (i.e., of diameter between 2 x 10-4 to 1 x 10-7 cm) in an insoluble medium. The particle of the dispersed substance are in discontinuous phase called dispersed phase; while insoluble medium or external phase in which they are distributed is called dispersion medium. Besides these, a colloidal solution some times have a stabilizing agent which keeps the colloidal particles apart, thereby avoiding their coalescence and consequent settling under the influence of gravity.
Types of Colloids
Dispersed phase |
Dispersion medium |
Name of Colloidal form |
Some examples |
1. Gas |
Liquid |
Foam or froth |
Foam, whipped cream, beaten egg whites, froth, lemonade, soap sol, detergent solution etc. |
2. Gas |
Solid |
Solid foam |
Pumic stone (air in silicates) floating, soaps, rubber, biscuit, cake, breads dough, lava, volcanic ash, styrene foam, etc. |
3. Liquid |
Gas |
Liquid aerosols |
mist, fog, clouds, insecticide spray etc. |
4. Liquid |
Liquid |
Emulsions |
Milk, emulsified oils, medicine, cream, mayonnaise, etc. |
5. Liquid |
Solid |
Gels |
Cheese, jellies, gel, curd, butter, boot polish, pearl (CaCO3 with water inclusions), etc. |
6. Solid |
Gas |
Solid aerosols |
Smoke, dust storm, fume, etc. |
7. Solid |
Liquid |
Sols |
Glue, Indian ink, some paints, starch dispersed in water, milk of magnesia, gold sol, sols of As2O3, S, Fe2O3 and AgCl in water, Fe(OH)3 sol, white of an egg etc. |
8. Solid |
Solid |
Solid sols |
Black diamond, ruby glass, some alloys and minerals, and synthetic gem, etc. |
Other Resourceful Topics
- Adsorption
- Colloids
- Hydrophilic and Hydrophobic Colloids
- Preparation Of Colloidal Solutions
- Dispersion Or Disintegration Methods
- Purification Of Colloidal Solutions
- Characteristics Of Colloidal Solutions
- Stability Of Colloids
- Reversible And Protective Colloids And Gold Number
- Emulsions
- Surfactants And Micelles
- Working Mechanism Of Soaps And Detergents
- Exercise 1
- Exercise 2
- Exercise 3
- Exercise 4
- Exercise 5
- Exercise 6